Abstract
La/Ce-partially double-filled and Co-charge-compensated (La_1−zCe_z)_0.8Fe_4−xCo_xSb₁₂ skutterudites were synthesized, and their thermoelectric properties were studied by varying the filling ratio and charge compensation. X-ray diffraction analysis revealed that the matrix phase was skutterudite and a secondary phase was determined to the marcasite FeSb₂. However, the formation of marcasite could be inhibited..... More

Abstract
Partially double-filled skutterudites were prepared via encapsulated melting and hot pressing processes. The skutterudite phase was successfully synthesized through partial double filling of La/Yb and substitution of Co. A small quantity of secondary phase (marcasite FeSb₂) was formed, but its formation was suppressed by increasing Co charge compensation. The marcasite..... More

Abstract
p-Type (La1−zNdz)0.8Fe4−xCoxSb12 skutterudites were prepared by partial double filling with La/Nd and charge compensation by substituting Co for Fe. The skutterudite phase was successfully synthesized using encapsulated melting, quenching, annealing and hot-pressing processes, but a small amount of the marcasite phase was identified. Partial filling within the filling fraction limit..... More

Abstract
P-type Ce/Yb-filled skutterudites were synthesized, and their charge transport and thermoelectric properties were investigated with partial double filling and charge compensation. In the case of (Ce1-zYbz)0.8Fe4Sb12 without Co substitution, the marcasite (FeSb2) phase formed alongside the skutterudite phase, but the generation of the marcasite phase was inhibited by increasing Co..... More

Abstract
Partially La/Pr-double-filled and Co-substituted (La_1−zPr_z)_0.8Fe_4−xCo_xSb₁₂ skutterudites were synthesized by encapsulated melting and vacuum hot pressing. (La,Pr)Sb₂ phases were not formed because the partial filling did not exceed the filling fraction limit, and the amount of secondary phase FeSb₂ also decreased as the Co content increased. Electrical conductivity decreased with increasing..... More

Abstract
(Ce_1-zNd_z)_yFe_4-xCo_xSb₁₂ skutterudites were prepared by encapsulated melting, annealing, and hot pressing. The formation of a marcasite phase (FeSb₂) was significantly suppressed by partially filling the voids with Ce/Nd and making a Co substitution at the Fe site. Both the Hall and the Seebeck coefficient values were positive, indicating that all..... More