Abstract
Skinnerite (Cu₃SbS₃) has recently attracted attention as a promising thermoelectric material because of its low thermal conductivity. In this study, we performed the solid-state synthesis of Fe-doped skinnerite Cu₃Sb_1-yFe_yS₃ (y = 0.02−0.06) using mechanical alloying and hot pressing, and examined the samples’ thermoelectric properties relative to Fe doping content. All..... More

Abstract
Ge-doped tetrahedrites Cu₁₂Sb_4-yGe_yS₁₃ (y = 0.1–0.4) were prepared using mechanical alloying and hot pressing. An X-ray diffraction analysis after mechanical alloying showed a single tetrahedrite phase without secondary phases. The tetrahedrite phase was stable after hot pressing at 723 K under 70 MPa. As the Ge content increased, the lattice..... More

Abstract
Tetrahedrite is a promising thermoelectric material mainly due to its low thermal conductivity, a consequence of its complicated crystal structure. However, tetrahedrite has a high hole concentration; therefore, optimizing carrier concentration through doping is required to maximize the power factor. In this study, Te-doped tetrahedrites Cu₁₂Sb_4-yTe_yS₁₃ (0.1 ≤ y ≤..... More