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Alleviating Mn<sup>3+</sup> Dissolution in ZnMn<sub>2</sub>O<sub>4</sub> Cathode for the Extended Cyclability via Particle Size Increase
Zn-ion 배터리용 ZnMn2O4 양극재의 입자 크기 증가를 통한 Mn3+ 용출 완화로 수명 증가
Jae Young Park, Young Mook Choi, Sang-Eun Chun
박재영, 최영묵, 전상은
Korean J. Met. Mater. 2023;61(12):923-932.   Published online 2023 Nov 30
DOI: https://doi.org/10.3365/KJMM.2023.61.12.923

Abstract
ZnMn2O4 (ZMO) cathode possesses a high theoretical capacity of 224 mAh g-1 and high operating voltage (1.9 V vs. Zn2+/Zn) for aqueous Zn–ion batteries. However, the disproportionation reaction of Mn3+ leads to Mn dissolution in the ZMO cathode, deteriorating lifespan. In this study, we attempted to reduce Mn dissolution by..... More

                
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